Unprecedented reductive cyclisation of salophen ligands to tetrahydroquinoxalines during metal complex formation
نویسندگان
چکیده
منابع مشابه
Unprecedented detection of inherent chirality in uranyl-salophen complexes.
In complexes with the uranyl dication salophen ligands are highly puckered. This implies that non-symmetrically substituted uranyl-salophen derivatives exist in principle as a pair of enantiomers. However, due to easy disrotations about the bonds connecting the phenoxide units to the imine carbons, the rate of interconversion between enantiomeric forms of simple, sterically unhindered compounds...
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2020
ISSN: 1359-7345,1364-548X
DOI: 10.1039/d0cc01192d